4-Fluoro-2-[(3-methylphenyl)iminomethyl]phenol
نویسندگان
چکیده
The title compound, C(14)H(12)FNO, crystallizes as the trans phenol-imine tautomer. The two benzene rings are essentially coplanar, being inclined to one another by 9.28 (7)°. This is at least in part due to the intra-molecular O-H⋯N hydrogen bond between the hy-droxy O atom and the imine N atom. The crystal structure is stabilized by an array of weak C-H⋯O and C-H⋯F inter-actions, which link the mol-ecules into a stable three-dimensional network.
منابع مشابه
4-[(3-Chloro-2-methylphenyl)iminomethyl]phenol
In the title compound, C(14)H(12)ClNO, the dihedral angle between the aromatic rings is 39.84 (7)°. In th crystal, mol-ecules are connected by O-H⋯N hydrogen bonds into chains parallel to [001]. In addition, a C-H⋯π contact occurs.
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The structure of the title compound, [Cd(3)Cl(6)(C(15)H(15)NO(2))(2)(CH(4)O)(2)](n), is based on a layered zigzag polymeric chain along the c axis. The Cd(II) ions are linked by double chlorine bridges alternating between one CdCl(4)(CH(3)OH)(2) and two CdCl(4)(C(15)H(15)NO(2)) octa-hedral coordination units. Additional intrachain N-H⋯O and O-H⋯Cl hydrogen-bond interactions stabilize this arran...
متن کامل(E)-4-Fluoro-2-[(4-hydroxyphenethyl)iminomethyl]phenol
The title compound, C(15)H(14)FNO(2), has an E conformation about the C=N bond, which facilitates the formation of an intra-molecular O-H⋯N hydrogen bond. The F atom is disordered over two adjacent sites in a 0.65 (7):0.35 (7) ratio. The dihedral angle between the benzene ring planes is 14.2 (2)°. In the crystal, mol-ecules are linked by O-H⋯O hydrogen bonds, forming C(14) [010] chains.
متن کامل2-[(E)-(4-Methylphenyl)iminomethyl]-6-(morpholin-4-ylmethyl)phenol
In the title compound, C(19)H(22)N(2)O(2), the morpholine ring adopts an almost perfect normal chair conformation with puckering parameters Q(T), θ and ϕ of 0.5642 (18) Å, 177.32 (17) and ϕ = 10 (4)°, respectively. The two benzene rings make a dihedral angle of 42.67 (8)° with each other. An intra-molecular O-H⋯N hydrogen bond helps to stabilize the mol-ecular conformation. Aromatic C-H⋯π inter...
متن کامل4-[(E)-(4-Methylphenyl)iminomethyl]phenol
In the title compound, C(14)H(13)NO, the two rings show significant deviation from coplanarity, with a dihedral angle between the two planes of 49.40 (5)°. The hy-droxy group is involved in an inter-molecular O-H⋯N hydrogen bond, forming an extended one-dimensional zigzag chain along (001).
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